TRIMETHYLSILYL(TRIMETHYLSILOXY)ACETATE

  • Name: TRIMETHYLSILYL(TRIMETHYLSILOXY)ACETATE
  • CAS: 33581-77-0
  • Purity: 99%
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Details

Reputable factory supply TRIMETHYLSILYL(TRIMETHYLSILOXY)ACETATE 33581-77-0 in bulk at low price

  • Molecular Formula: C8H20O3Si2
  • Molecular Weight: 220.416
  • Appearance/Colour: Clear to straw liquid with distinct mild odor 
  • Vapor Pressure: 1.09mmHg at 25°C 
  • Refractive Index: n20/D 1.411(lit.)  
  • Boiling Point: 176.5 °C at 760 mmHg 
  • Flash Point: 50.5 °C 
  • PSA： 35.53000 
  • Density: 0.911 g/cm3 
  • LogP: 2.21600 

TRIMETHYLSILYL(TRIMETHYLSILOXY)ACETATE(Cas 33581-77-0) Usage

InChI:InChI=1/C8H20O3Si2/c1-12(2,3)10-7-8(9)11-13(4,5)6/h7H2,1-6H3

33581-77-0 Relevant articles

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Wissner

, p. 2749 (1978)

-

Incorporation of 18O into Glycolic Acid Obtained from the Bleomycin-Mediated Degradation of DNA: Evidence for 4'-Radical Trapping by 18O2

McGall, G. H.,Rabow, L. E.,Stubbe, J.

, p. 2836 - 2837 (1987)

-

Beta-lactam synthesis

-

Page/Page column 10, (2008/06/13)

The present invention is directed to a p...

Synthesis and anti-tubulin activity of a 3′-(4-Azidophenyl)-3′- dephenylpaclitaxel photoaffinity probe

Spletstoser, Jared T.,Flaherty, Patrick T.,Himes, Richard H.,Georg, Gunda I.

, p. 6459 - 6465 (2007/10/03)

The synthesis and biological evaluation ...

Identification of products containing -COOH, -OH, and -C=O in atmospheric oxidation of hydrocarbons

Yu, Jianzhen,Flagan, Richard C.,Seinfeld, John H.

, p. 2357 - 2370 (2007/10/03)

Atmospheric oxidation of hydrocarbons by...

33581-77-0 Process route

glycolic Acid
79-14-1

glycolic Acid

glycolide
502-97-6

glycolide

trimethylsilyl [(trimethylsilyl)oxy]acetate
33581-77-0

trimethylsilyl [(trimethylsilyl)oxy]acetate

C<sub>10</sub>H<sub>22</sub>O<sub>5</sub>Si<sub>2</sub>

C10 H22 O5 Si2

Conditions
Conditions Yield
With trimethylsilylating agent; Product distribution; multistep reaction: 1.) 125 deg C, 6 h, 2.) trimethylsilylation; further temperature, time effect;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

glycolic Acid
79-14-1

glycolic Acid

trimethylsilyl [(trimethylsilyl)oxy]acetate
33581-77-0

trimethylsilyl [(trimethylsilyl)oxy]acetate

Conditions
Conditions Yield
With pyridine; In acetonitrile; for 1h; Product distribution / selectivity;
91%
Multistep reaction; (i) HN(SiMe3)2, Py, (ii) /BRN= 1209232/;
With pyridine; dmap; In dichloromethane; for 1h;
With pyridine; In n-heptane; at 0 - 40 ℃; for 0.5h; Product distribution / selectivity;

33581-77-0 Upstream products

  • 75-77-4
    75-77-4

    chloro-trimethyl-silane

  • 79-14-1
    79-14-1

    glycolic Acid

  • 999-97-3
    999-97-3

    1,1,1,3,3,3-hexamethyl-disilazane

  • 25561-30-2
    25561-30-2

    N,O-Bis(trimethylsilyl)trifluoroacetamide

33581-77-0 Downstream products

  • 69097-20-7
    69097-20-7

    tris(trimethylsilyloxy)ethylene

  • 107053-35-0
    107053-35-0

    2-cyclohexyl-1,3-dioxolan-4-one

  • 138901-73-2
    138901-73-2

    5-Phenyl-1,4,6,9-tetraoxa-5λ5 -phospha-spiro[4.4]nonane-2,7-dione

  • 138901-74-3
    138901-74-3

    5-(2,5-Dimethyl-phenyl)-1,4,6,9-tetraoxa-5λ5 -phospha-spiro[4.4]nonane-2,7-dione

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